Fast Determination of Uranium and Radium in Water of variable Composition

Ayranov, Marin; Krähenbühl, Urs; Schneider, Uwe (2006). Fast Determination of Uranium and Radium in Water of variable Composition. Czechoslovak journal of physics, 56(Supplement 4), D219-D227. Praha: Academy of Sciences of the Czech Republic 10.1007/s10582-006-0508-5

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The effects of uranium and its progeny radium are known to be harmful and their measurements in drinking water are necessary for careful monitoring. Fast and accurate methods for determination of uranium and radium in water samples with various salinity and activities concentrations have been developed. High Resolution Inductively Coupled Plasma Mass Spectrometry is used for direct measurement of uranium. Calibration is performed with 238U standards and 209Bi is used as internal standard to correct the matrix effects and plasma instability. The radium is determined by photon electron rejected alpha liquid spectrometry after a chemical separation procedure that includes co-precipitation of radium with barium sulphate, transformation of the sulphate to carbonate and extraction of radium in the scintillation cocktail. The minimal detectable activities of 3.5×10−8 Bq kg−1 for uranium and 2.3×10−4 Bq kg−1 for radium are obtained.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP)

UniBE Contributor:

Krähenbühl, Urs

ISSN:

0011-4626

Publisher:

Academy of Sciences of the Czech Republic

Language:

English

Submitter:

Factscience Import

Date Deposited:

04 Oct 2013 14:44

Last Modified:

05 Dec 2022 14:13

Publisher DOI:

10.1007/s10582-006-0508-5

Web of Science ID:

000206057500027

BORIS DOI:

10.48350/18313

URI:

https://boris.unibe.ch/id/eprint/18313 (FactScience: 310)

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