Povie, G.; Villa, G.; Ford, L.; Pozzi, D.; Schiesser, C.H.; Renaud, Philippe (2010). Role of catechol in the radical reduction of B-alkylcatecholboranes in presence of methanol. Chemical communications, 46(5), pp. 803-805. Cambridge: Royal Society of Chemistry 10.1039/b917004a
Full text not available from this repository. (Request a copy)Mechanistic investigations on the previously reported reduction of B-alkylcatecholboranes in the presence of methanol led to the disclosure of a new
mechanism involving catechol as a reducing agent. More than just revising the mechanism of this reaction, we disclose here the surprising role of catechol, a chain
breaking antioxidant, which becomes a source of hydrogen atoms in an efficient radical chain process
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Renaud, Philippe |
ISSN: |
1359-7345 |
Publisher: |
Royal Society of Chemistry |
Language: |
English |
Submitter: |
Factscience Import |
Date Deposited: |
04 Oct 2013 14:17 |
Last Modified: |
05 Dec 2022 14:04 |
Publisher DOI: |
10.1039/b917004a |
Web of Science ID: |
000274207000042 |
URI: |
https://boris.unibe.ch/id/eprint/5180 (FactScience: 209904) |
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