Ferlay, Sylvie; Francese, Giancarlo; Schmalle, Helmut W.; Decurtins, Silvio (1999). A new bidimensional compound containing (μ-thiocyanate)(bpy)copper(II) molecules: synthesis, crystal structure and magnetic properties of [Cu(bpy)(NCS)2]n (bpy = 2,2'-bipyridyl). Inorganica chimica acta, 286(1), pp. 108-113. Elsevier Sequoia
Full text not available from this repository. (Request a copy)The crystal structure of the first bidimensional copper(II) compound containing only thiocyanate as bridging ligands [Cu(bpy)(NCS) 2 ] n , where bpy=2,2'-bipyridyl, has been determined by X-ray diffraction on single-crystals. Two different environments for both types of copper(II) ions in the unit cell are apparent: a distorted octahedron and a square pyramid. A bidimensional structure with a deformed honeycomb-layer motif is formed, the bipyridyl ligands filling the interlayer space. The magnetic susceptibility data of the compound have been investigated between 280 and 1.8 K. The compound presents a very weak antiferromagnetic interaction that has been fitted by using the Bleaney-Bowers expression for a dimeric unit, whereby a J value of -1.01(1) cm - 1 (H=-JS 1 .S 2 ) and a g value of 2.08(1) have been obtained.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Decurtins, Silvio |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry |
ISSN: |
0020-1693 |
Publisher: |
Elsevier Sequoia |
Language: |
English |
Submitter: |
Silvio Decurtins |
Date Deposited: |
08 Jun 2015 11:25 |
Last Modified: |
05 Dec 2022 14:47 |
URI: |
https://boris.unibe.ch/id/eprint/69141 |
Actions (login required)
 |
Edit item |