McDonald, Chriss E; Ramsey, Jeremy D; Sampsell, David G; Butler, Julie A; Cecchini, Michael R (2010). Tripyrrolidinophosphoric acid triamide as an activator in samarium diiodide reductions. Organic letters, 12(22), pp. 5178-81. Washington, D.C.: American Chemical Society 10.1021/ol102040s
Full text not available from this repository. (Request a copy)The electrochemical and spectrophotometric characterization of the complex formed from samarium diiodide and 4 equiv of tripyrrolidinophosphoric acid triamide (TPPA) is presented. Kinetic studies indicate that the SmI(2)/TPPA complex possesses reactivity greater than the complex formed between samarium diiodide and 4 equiv of HMPA. Examples of the use of SmI(2)/TPPA in synthesis are presented.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
04 Faculty of Medicine > Department of Dermatology, Urology, Rheumatology, Nephrology, Osteoporosis (DURN) > Clinic of Urology |
UniBE Contributor: |
Cecchini, Marco Giovanni |
ISSN: |
1523-7060 |
Publisher: |
American Chemical Society |
Language: |
English |
Submitter: |
Factscience Import |
Date Deposited: |
04 Oct 2013 14:10 |
Last Modified: |
05 Dec 2022 14:00 |
Publisher DOI: |
10.1021/ol102040s |
PubMed ID: |
20979412 |
Web of Science ID: |
000284080400025 |
URI: |
https://boris.unibe.ch/id/eprint/1245 (FactScience: 202399) |
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