Early stage weathering systematics of Pb and Nd isotopes derived from a high-Alpine Holocene lake sediment record

Süfke, Finn; Gutjahr, Marcus; Gilli, Adrian; Anselmetti, Flavio S.; Glur, Lukas; Eisenhauer, Anton (2019). Early stage weathering systematics of Pb and Nd isotopes derived from a high-Alpine Holocene lake sediment record. Chemical geology, 507, pp. 42-53. Elsevier 10.1016/j.chemgeo.2018.12.026

[img] Text
Suefke.pdf - Published Version
Restricted to registered users only
Available under License Publisher holds Copyright.

Download (3MB) | Request a copy

Radiogenic Pb and Nd isotopes are well established tools in paleoceanographic science tracing ambient climate and continental runoff to the oceans down to sub-millennial timescales. Particularly in case of Pb isotopes, a clear climate dependency of continental isotopic runoff on glacial-interglacial transitions has been observed. Pb isotopes were reported to be released incongruently during initial chemical weathering. This incongruent release implies that Pb isotopic runoff compositions differ from the bulk catchment Pb isotopic signal. Yet only little is known about the processes leading to the incongruent release and the timescales of weathering on the con- tinents. In this study we targeted the adsorbed trace metal signature in sediments from a Swiss high-Alpine lake that have accumulated since the retreat of the large Alpine ice domes during the last deglaciation to investigate initial Pb and Nd isotope weathering processes in a granitic environment. Additionally, selected adsorbed ele- ment concentrations and ratios were analysed to complement the isotopic physico-chemical weathering in- formation. The integrity of the presented isotope records is supported by further investigation into the lake environment (e.g. oxic/anoxic conditions) and its potential influence on the isotopic record. The Pb isotope records during the early lake phase witnessed high-amplitude isotopic fluctuations linked to the initial chemical weathering of fine glacial substrate. This finding is also supported by the lithology of the core and rapidly decreasing adsorbed Th and U concentrations. Following this early lake phase, the majority of the Holocene traced congruent release of 207Pb/204Pb and 206Pb/204Pb and a significant depletion of 208Pb/204Pb in the ad- sorbed phase. These findings corroborate earlier suggestions of more effective weathering of uranogenic mi- nerals yet also call for the presence of more weathering-resistant thorogenic minerals in the lake catchment. The latest 2.2 ka of the record are significantly overprinted by anthropogenic Pb deposition coinciding with the rise and fall of the Roman Empire. Finally, our data suggest that Nd isotopes are equally affected by incongruent weathering during the initial deglacial weathering processes, albeit at smaller magnitude than seen for Pb isotopes.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Institute of Geological Sciences
08 Faculty of Science > Institute of Geological Sciences > Quaternary Geology

UniBE Contributor:

Anselmetti, Flavio

Subjects:

500 Science > 550 Earth sciences & geology

ISSN:

0009-2541

Publisher:

Elsevier

Language:

English

Submitter:

Flavio Anselmetti

Date Deposited:

11 Jun 2019 14:01

Last Modified:

24 Oct 2019 04:02

Publisher DOI:

10.1016/j.chemgeo.2018.12.026

BORIS DOI:

10.7892/boris.129863

URI:

https://boris.unibe.ch/id/eprint/129863

Actions (login required)

Edit item Edit item
Provide Feedback