Nanographene Favors Interactions with the Electron Acceptor Rather Than the Electron Donor in a Planar Fused Push-Pull Conjugate

Zhou, Ping; Michel, Volland; Leonie, Wibmer; Häner, Robert; Decurtins, Silvio; Liu, Shi-Xia; Guldi, Dirk M. (6 September 2019). Nanographene Favors Interactions with the Electron Acceptor Rather Than the Electron Donor in a Planar Fused Push-Pull Conjugate (Unpublished). In: Swiss Chemical Society Fall Meeting 2019. September 6, 2019.

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Dispersions of preexfoliated nanographene (NG) and fused electron donor–acceptor tetrathiafulvalene–perylenediimide (TTF–PDI) enable multifunctional, noncovalently functionalized NG. They were characterized by complementary spectroscopic and microscopic techniques. The design strategy of the chromophoric and electroactive molecular conjugate renders a large and planar π-extended system with a distinct localization of electron-rich and electron-poor parts at either end of the molecular conjugate. Within the in-situ formed nanohybrid, the conjugate was found to couple electronically with NG preferentially through the electron accepting PDI rather than the electron donating TTF and to lead to p-doping of graphene.

Item Type:

Conference or Workshop Item (Poster)

Division/Institute:

08 Faculty of Science > Departement of Chemistry and Biochemistry

UniBE Contributor:

Zhou, Ping; Häner, Robert; Decurtins, Silvio and Liu, Shi-Xia

Subjects:

500 Science > 570 Life sciences; biology
500 Science > 540 Chemistry

Language:

English

Submitter:

Ping Zhou

Date Deposited:

07 Jan 2020 15:07

Last Modified:

07 Jan 2020 15:07

BORIS DOI:

10.7892/boris.137513

URI:

https://boris.unibe.ch/id/eprint/137513

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