Hupf, Emanuel; Malaspina, Lorraine A.; Holsten, Sebastian; Kleemiss, Florian; Edwards, Alison J.; Price, Jason R.; Kozich, Valeri; Heyne, Karsten; Mebs, Stefan; Grabowsky, Simon; Beckmann, Jens (2019). Proximity Enforced Agostic Interactions Involving Closed-Shell Coinage Metal Ions. Inorganic chemistry, 58(24), pp. 16372-16378. American Chemical Society 10.1021/acs.inorgchem.9b01845
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A proximity enforcing diarylsilane ligand is reported, which gives rise to unusual Si−H···M interactions with the d10 metal ions Cu+ and Ag+ upon complexation. These interactions are studied in detail both experimentally and computationally and can be classified to be weakly agostic in nature for the Si−H···Cu interaction. The Si−H···Ag interaction has more signatures of an electrostatic contact.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Malaspina, Lorraine, Kleemiss, Florian, Grabowsky, Simon |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry |
ISSN: |
0020-1669 |
Publisher: |
American Chemical Society |
Language: |
English |
Submitter: |
Simon Grabowsky |
Date Deposited: |
07 Apr 2020 08:07 |
Last Modified: |
05 Dec 2022 15:37 |
Publisher DOI: |
10.1021/acs.inorgchem.9b01845 |
PubMed ID: |
31747261 |
BORIS DOI: |
10.7892/boris.142469 |
URI: |
https://boris.unibe.ch/id/eprint/142469 |
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