Proximity Enforced Agostic Interactions Involving Closed-Shell Coinage Metal Ions

Hupf, Emanuel; Malaspina, Lorraine A.; Holsten, Sebastian; Kleemiss, Florian; Edwards, Alison J.; Price, Jason R.; Kozich, Valeri; Heyne, Karsten; Mebs, Stefan; Grabowsky, Simon; Beckmann, Jens (2019). Proximity Enforced Agostic Interactions Involving Closed-Shell Coinage Metal Ions. Inorganic chemistry, 58(24), pp. 16372-16378. American Chemical Society 10.1021/acs.inorgchem.9b01845

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A proximity enforcing diarylsilane ligand is reported, which gives rise to unusual Si−H···M interactions with the d10 metal ions Cu+ and Ag+ upon complexation. These interactions are studied in detail both experimentally and computationally and can be classified to be weakly agostic in nature for the Si−H···Cu interaction. The Si−H···Ag interaction has more signatures of an electrostatic contact.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Departement of Chemistry and Biochemistry

UniBE Contributor:

Kleemiss, Florian and Grabowsky, Simon

Subjects:

500 Science > 570 Life sciences; biology
500 Science > 540 Chemistry

ISSN:

0020-1669

Publisher:

American Chemical Society

Language:

English

Submitter:

Simon Grabowsky

Date Deposited:

07 Apr 2020 08:07

Last Modified:

07 Apr 2020 08:07

Publisher DOI:

10.1021/acs.inorgchem.9b01845

PubMed ID:

31747261

BORIS DOI:

10.7892/boris.142469

URI:

https://boris.unibe.ch/id/eprint/142469

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