Micro-X-ray diffraction and chemical mapping of aged interfaces between cement pastes and Opalinus Clay

Bernard, Ellina; Jenni, Andreas; Fisch, Martin; Grolimund, Daniel; Mäder, Urs (2020). Micro-X-ray diffraction and chemical mapping of aged interfaces between cement pastes and Opalinus Clay. Applied geochemistry, 115, p. 104538. Elsevier 10.1016/j.apgeochem.2020.104538

Preview	Text AG_2020_Bernard_XRDmaps_interfaces.pdf - Accepted Version Available under License Creative Commons: Attribution-Noncommercial-No Derivative Works (CC-BY-NC-ND). Download (7MB) | Preview
	Text 1-s2.0-S0883292720300196-main.pdf - Published Version Restricted to registered users only Available under License Publisher holds Copyright. Download (8MB)

The safety of a geological repository designed for deep storage of nuclear waste rests on the long-lived isolation properties of the geological environment and the engineered barrier system. To study the chemical and physical behaviour of cementitious/clayey interfaces, such interfaces have been collected during repeat sampling campaigns of the CI Experiment (Cement-Clay Interaction Experiment) at the Mont Terri rock laboratory (St. Ursanne, Switzerland, www.mont-terri.ch) over the last decade. This study focuses on the advanced analysis by µ-XRD mapping to locate and identify the mineral phases on each side of the interface. The hydrates as portlandite, ettringite and C-S-H present in the Portland cement (PC) were dissolved in contact with the Opalinus Clay (OPA) up to different depths (~0.2 mm for portlandite; ~1 mm for ettringite; completely depleted for C-S-H up to 0.1 mm and less visible on a 1-mm-depth) while the ettringite from ESDRED (a low-pH cement type) seems to be destabilized to a larger depth ( ≥ 3 mm ). In contrast to former studies, calcite could not be clearly observed at the interface PC - OPA but was well developed at the interface ESDRED - OPA. The extent of reaction after 10 years is very small in both cases, and dissolution of clay minerals remains below detection. The identification of mineral phases involved in reactions facilitates the understanding of the processes, thus, will help to improve the reactive transport models used to simulate the evolution over long times.

Interest & Impact

Downloads

128 since deposited on 28 May 2020
57 in the past 12 months

Citations

5 Citations in Web of Science ®
6 Citations in Scopus

Search

in Google Scholar™

Services

Actions (login required)

Edit item

Actions (login required)

Edit item