Di Giovannantonio, Marco; Chen, Qiang; Urgel, José I.; Ruffieux, Pascal; Pignedoli, Carlo A.; Müllen, Klaus; Narita, Akimitsu; Fasel, Roman (2020). On-Surface Synthesis of Oligo(indenoindene). Journal of the American Chemical Society, 142(30), pp. 12925-12929. American Chemical Society 10.1021/jacs.0c05701
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Fully conjugated ladder polymers (CLP) possess unique optical and electronic properties, and are considered promis-ing materials for applications in (opto)electronic devices. Poly(indenoindene) is a CLP consisting of an alternating array of five- and six-membered rings, which has remained elusive so far. Here, we report an on-surface synthesis of oligo(indenoindene) on Au(111). Its structure and a low elec-tronic bandgap have been elucidated by low-temperature scanning tunneling microscopy and spectroscopy and non-contact atomic force microscopy, complemented by density functional theory calculations. Achieving defect-free seg-ments of oligo(indenoindene) offers an exclusive insight into this CLP and provides the basis to further synthetic approaches.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Fasel, Roman |
Subjects: |
500 Science > 530 Physics 500 Science > 540 Chemistry |
ISSN: |
0002-7863 |
Publisher: |
American Chemical Society |
Language: |
English |
Submitter: |
Roman Fasel |
Date Deposited: |
03 Sep 2020 16:23 |
Last Modified: |
05 Dec 2022 15:40 |
Publisher DOI: |
10.1021/jacs.0c05701 |
BORIS DOI: |
10.7892/boris.146337 |
URI: |
https://boris.unibe.ch/id/eprint/146337 |
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