On‐surface Synthesis of a Chiral Graphene Nanoribbon with Mixed Edge Structure

Keerthi, Ashok; Sánchez‐Sánchez, Carlos; Deniz, Okan; Ruffieux, Pascal; Schollmeyer, Dieter; Feng, Xinliang; Narita, Akimitsu; Fasel, Roman; Müllen, Klaus (2020). On‐surface Synthesis of a Chiral Graphene Nanoribbon with Mixed Edge Structure. Chemistry - an Asian journal, 15(22), pp. 3807-3811. Wiley-VCH 10.1002/asia.202001008

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Chiral graphene nanoribbons represent an important class of graphene nanomaterials with varying combinations of armchair and zigzag edges conferring them unique structure‐dependent electronic properties. Here, we describe the on‐surface synthesis of an unprecedented cove‐edge chiral GNR with a benzo‐fused backbone on a Au(111) surface using 2,6‐dibromo‐1,5‐diphenylnaphthalene as precursor. The initial precursor self‐assembly and the formation of the chiral GNRs upon annealing are revealed, along with a relatively small electronic bandgap of approximately 1.6 eV, by scanning tunnelling microscopy and spectroscopy.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP)

UniBE Contributor:

Fasel, Roman

Subjects:

500 Science > 570 Life sciences; biology
500 Science > 540 Chemistry
500 Science > 530 Physics

ISSN:

1861-4728

Publisher:

Wiley-VCH

Language:

English

Submitter:

Roman Fasel

Date Deposited:

03 Feb 2021 14:53

Last Modified:

05 Dec 2022 15:45

Publisher DOI:

10.1002/asia.202001008

BORIS DOI:

10.48350/151487

URI:

https://boris.unibe.ch/id/eprint/151487

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