Ahmadi, Fereshteh; Goli, Hamid Reza; Balmohammadi, Yaser; Bazgir, Ayoob (2021). Isocyanide Insertion–Cyclization Reaction for Imidazoisoindol-5-imine Scaffold Synthesis: A Selective Solvatochromic Fluorescent Probe for Methanol Detection. Journal of organic chemistry, 86(1), pp. 146-152. American Chemical Society 10.1021/acs.joc.0c01860
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An efficient, ligand-free, and Pd-catalyzed method for the synthesis of imidazoisoindole imine scaffolds with satisfactory yields via C–C and C–N bond formation has been developed. The synthesized scaffolds have unique potential for selective MeOH detection from other solvents, especially EtOH. The appealing features of this transformation are phosphinic ligand-free conditions, the use of a small amount of Pd(OAc)2, and a practical procedure for the synthesis of imidazoisoindole imine scaffolds.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Balmohammadi, Yaser |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry |
ISSN: |
0022-3263 |
Publisher: |
American Chemical Society |
Language: |
English |
Submitter: |
Simon Grabowsky |
Date Deposited: |
03 Jun 2021 16:46 |
Last Modified: |
05 Dec 2022 15:51 |
Publisher DOI: |
10.1021/acs.joc.0c01860 |
BORIS DOI: |
10.48350/156432 |
URI: |
https://boris.unibe.ch/id/eprint/156432 |
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