Unveiling the origin of photo-induced enhancement of oxidation catalysis at Mo( vi ) centres of Ru( ii )–Mo( vi ) dyads

Nazari Haghighi Pashaki, Maryam; Choi, Tae-Kyu; Rohwer, Egmont J.; Feurer, Thomas; Duhme-Klair, Anne-Kathrin; Gawelda, Wojciech; Cannizzo, Andrea (2021). Unveiling the origin of photo-induced enhancement of oxidation catalysis at Mo( vi ) centres of Ru( ii )–Mo( vi ) dyads. Chemical communications, 57(34), pp. 4142-4145. Royal Society of Chemistry 10.1039/d1cc00750e

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Photo-induced oxidation-enhancement in biomimetic bridged Ru(II)–Mo(VI) photo-catalyst is unexpectedly photo-activated in ps timescales. One-photon absorption generates an excited state where both photo-oxidized and photo-reduced catalytic centres are activated simultaneously and independently.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Institute of Applied Physics
08 Faculty of Science > Institute of Applied Physics > Lasers

UniBE Contributor:

Nazari Haghighi Pashaki, Maryam; Feurer, Thomas and Cannizzo, Andrea

Subjects:

600 Technology > 620 Engineering
500 Science
500 Science > 530 Physics

ISSN:

1359-7345

Publisher:

Royal Society of Chemistry

Language:

English

Submitter:

Simone Corry

Date Deposited:

21 Jun 2021 14:20

Last Modified:

21 Jun 2021 14:28

Publisher DOI:

10.1039/d1cc00750e

BORIS DOI:

10.48350/156824

URI:

https://boris.unibe.ch/id/eprint/156824

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