Xu, Xiushang; Kinikar, Amogh; Di Giovannantonio, Marco; Ruffieux, Pascal; Müllen, Klaus; Fasel, Roman; Narita, Akimitsu (2021). On-Surface Synthesis of Dibenzohexacenohexacene and Dibenzopentaphenoheptaphene. Bulletin of the Chemical Society of Japan, 94(3), pp. 997-999. The Chemical Society of Japan 10.1246/bcsj.20200382
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21_Xu_On-Surface_Synthesis_of_Dibenzohexacenohexacene_and_Dibenzopentaphenoheptaphene.pdf - Published Version Restricted to registered users only Available under License Publisher holds Copyright. Download (1MB) |
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We report the on-surface synthesis and gas-phase theoretical studies of two novel nanographenes, namely, dibenzohexacenohexacene and dibenzopentaphenoheptaphene, using 8,8'-dibromo-5,5'-bibenzo[rst]pentaphene as a precursor. These nanographenes display a combination of armchair and zigzag edges, as shown by noncontact atomic force microscopy (nc-AFM), and their electronic properties are elucidated by density functional theory (DFT) calculations which reveal relatively low HOMO-LUMO energy gaps of about 1.75 eV.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Fasel, Roman |
Subjects: |
500 Science > 530 Physics 500 Science > 540 Chemistry |
ISSN: |
0009-2673 |
Publisher: |
The Chemical Society of Japan |
Language: |
English |
Submitter: |
Roman Fasel |
Date Deposited: |
15 Feb 2022 17:06 |
Last Modified: |
05 Dec 2022 16:05 |
Publisher DOI: |
10.1246/bcsj.20200382 |
BORIS DOI: |
10.48350/164868 |
URI: |
https://boris.unibe.ch/id/eprint/164868 |
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