Valenta, Leoš; Mayländer, Maximilian; Kappeler, Pia; Blacque, Olivier; Šolomek, Tomáš; Richert, Sabine; Juríček, Michal (2022). Trimesityltriangulene: a persistent derivative of Clar's hydrocarbon. Chemical communications, 58(18), pp. 3019-3022. Royal Society of Chemistry 10.1039/d2cc00352j
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Triangulene, known as Clar's hydrocarbon, is a prototypical non-Kekulé diradical comprised of six benzenoid rings fused in a triangular shape. We synthesized and characterized its trimesityl derivative, illustrating that three bulky substituents installed in the centers of the zigzag edges suffice to protect all reactive positions. This work brings prospects to use triangulene and its open-shell analogs in spintronic materials via solution-phase synthesis.
Item Type: |
Journal Article (Original Article) |
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Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Solomek, Tomás |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry |
ISSN: |
1359-7345 |
Publisher: |
Royal Society of Chemistry |
Language: |
English |
Submitter: |
Pubmed Import |
Date Deposited: |
21 Feb 2022 15:13 |
Last Modified: |
05 Dec 2022 16:09 |
Publisher DOI: |
10.1039/d2cc00352j |
PubMed ID: |
35156113 |
BORIS DOI: |
10.48350/165813 |
URI: |
https://boris.unibe.ch/id/eprint/165813 |
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