VIS spectroscopy of NaCl – water ice mixtures irradiated with 1 and 5 keV electrons under Europa's conditions: Formation of colour centres and Na colloids

Cerubini, R.; Pommerol, A.; Galli, A.; Jost, B.; Wurz, P.; Thomas, N. (2022). VIS spectroscopy of NaCl – water ice mixtures irradiated with 1 and 5 keV electrons under Europa's conditions: Formation of colour centres and Na colloids. Icarus, 379, p. 114977. Elsevier 10.1016/j.icarus.2022.114977

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Recent laboratory efforts and telescopic observations of Europa have shown the relevance of a yellow colouration of sodium chloride (NaCl) caused by crystal defects generated by irradiation. We further investigate this process by irradiating (with energetic electrons) different types of analogues where NaCl is associated in different ways to water ice. We produce two types of icy analogues: compact slabs and granular particles where we investigate two particle sizes (5 and 70 μm). We perform electron irradiation at cryogenic temperatures (100K) and under high vacuum (10−7 mbar) conditions, with energies of 1 and 5 keV. We observe the formation of two different types of colour centres. The so-called F-centres (460 nm) were formed in every sample, but the intensity of the absorption band within the compact slabs surpassed any other icy analogues and was comparable to the intensity of the absorption band within pure NaCl grains. M-centres (720 nm) have not been detected at the surface of Europa so far, and were close to the detection limit during our irradiation of compact slabs. The slabs could be good analogues for Europa's surface as they produce mainly F-centres. Other notable differences have been observed between compact slabs and granular samples, such as the presence of an absorption band at 580 nm attributed to colloids of Na, exclusively within granular samples. Such absorptions have not been reported in previous studies.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Physics Institute > Space Research and Planetary Sciences
08 Faculty of Science > Physics Institute
08 Faculty of Science > Physics Institute > NCCR PlanetS

UniBE Contributor:

Cerubini, Romain Ivan Valentin, Pommerol, Antoine, Galli, A, Wurz, Peter, Thomas, Nicolas

Subjects:

500 Science > 520 Astronomy
600 Technology > 620 Engineering

ISSN:

0019-1035

Publisher:

Elsevier

Language:

English

Submitter:

Dora Ursula Zimmerer

Date Deposited:

09 Jun 2022 07:50

Last Modified:

05 Dec 2022 16:20

Publisher DOI:

10.1016/j.icarus.2022.114977

BORIS DOI:

10.48350/170517

URI:

https://boris.unibe.ch/id/eprint/170517

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