Circularly Polarized Luminescence in a Möbius Helicene Carbon Nanohoop.

Malinčík, Juraj; Gaikwad, Sudhakar; Mora-Fuentes, Juan P; Boillat, Marc-Aurèle; Prescimone, Alessandro; Häussinger, Daniel; Campaña, Araceli G; Šolomek, Tomáš (2022). Circularly Polarized Luminescence in a Möbius Helicene Carbon Nanohoop. Angewandte Chemie (International ed.), 61(37), e202208591. Wiley-VCH 10.1002/anie.202208591

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We present the first helicene carbon nanoohop that integrates a [6]helicene into [7]cycloparaphenylene. The [6]helicene endows the helicene carbon nanohoop with chiroptical properties and configurational stability typical for higher helicenes, while the radially conjugated seven para -phenylenes largely determine the optoelectronic properties. The structure of the helicene carbon nanoohop was unambiguously characterized by NMR, MS and X-ray analysis that revealed that it possesses a topology of a Möbius strip in the solid state and in solution. The chirality transfers from the [6]helicene to the para -phenylenes and leads to a pronounced circular dichroism and bright circularly polarized luminescence, which is affected by the structural topology of the nanohoop.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP)

UniBE Contributor:

Solomek, Tomás

Subjects:

500 Science > 570 Life sciences; biology
500 Science > 540 Chemistry

ISSN:

1433-7851

Publisher:

Wiley-VCH

Language:

English

Submitter:

Pubmed Import

Date Deposited:

25 Jul 2022 12:50

Last Modified:

21 Jul 2023 00:25

Publisher DOI:

10.1002/anie.202208591

PubMed ID:

35856293

Uncontrolled Keywords:

Circularly Polarized Luminescence Möbius topology chirality cycloparaphenylenes helicenes

BORIS DOI:

10.48350/171488

URI:

https://boris.unibe.ch/id/eprint/171488

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