Stroek, Wowa; Hoareau, Lilian; Albrecht, Martin (2023). From the bottle: simple iron salts for the efficient synthesis of pyrrolidines via catalytic C-H bond amination. Catalysis science & technology, 13(4), pp. 958-962. Royal Society of Chemistry 10.1039/d2cy02065c
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Commercially available iron salts FeX2 are remarkably active catalysts for pyrrolidine formation from organic azides via direct C-H bond amination. With FeI2, amination is fast and selective, (<30 min for 80% yield at 2 mol% loading), TONs up to 370 are reached with just 0.1 mol% catalyst, different functional groups are tolerated, and a variety of C-H bonds were activated.
Item Type: |
Journal Article (Original Article) |
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Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Hoareau, Lilian, Albrecht, Martin |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry 000 Computer science, knowledge & systems |
ISSN: |
2044-4753 |
Publisher: |
Royal Society of Chemistry |
Language: |
English |
Submitter: |
Pubmed Import |
Date Deposited: |
02 Mar 2023 14:17 |
Last Modified: |
02 Mar 2023 23:37 |
Publisher DOI: |
10.1039/d2cy02065c |
PubMed ID: |
36825222 |
BORIS DOI: |
10.48350/179233 |
URI: |
https://boris.unibe.ch/id/eprint/179233 |
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