Continuous measurements of methane mixing ratios from ice cores

Stowasser, C.; Buizert, C.; Gkinis, V.; Chappellaz, J.; Schüpbach, Simon; Bigler, Matthias; Faïn, X.; Sperlich, P.; Baumgartner, Matthias; Schilt, Adrian (2012). Continuous measurements of methane mixing ratios from ice cores. Atmospheric Measurement Techniques (AMT), 5(5), pp. 999-1013. Göttingen: Copernicus Publications 10.5194/amt-5-999-2012

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This work presents a new, field-deployable technique for continuous, high-resolution measurements of methane mixing ratios from ice cores. The technique is based on a continuous flow analysis system, where ice core samples cut along the long axis of an ice core are melted continuously. The past atmospheric air contained in the ice is separated from the melt water stream via a system for continuous gas extraction. The extracted gas is dehumidified and then analyzed by a Wavelength Scanned-Cavity Ring Down Spectrometer for methane mixing ratios. We assess the performance of the new measurement technique in terms of precision (±0.8 ppbv, 1σ), accuracy (±8 ppbv), temporal (ca. 100 s), and spatial resolution (ca. 5 cm). Using a firn air transport model, we compare the resolution of the measurement technique to the resolution of the atmospheric methane signal as preserved in ice cores in Greenland. We conclude that our measurement technique can resolve all climatically relevant variations as preserved in the ice down to an ice depth of at least 1980 m (66 000 yr before present) in the North Greenland Eemian Ice Drilling ice core. Furthermore, we describe the modifications, which are necessary to make a commercially available spectrometer suitable for continuous methane mixing ratio measurements from ice cores.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Physics Institute > Climate and Environmental Physics

UniBE Contributor:

Schüpbach, Simon; Bigler, Matthias; Baumgartner, Matthias and Schilt, Adrian

Subjects:

500 Science > 530 Physics

ISSN:

1867-1381

Publisher:

Copernicus Publications

Language:

English

Submitter:

Factscience Import

Date Deposited:

04 Oct 2013 14:43

Last Modified:

03 Jan 2015 05:13

Publisher DOI:

10.5194/amt-5-999-2012

Web of Science ID:

000304057300007

BORIS DOI:

10.7892/boris.17996

URI:

https://boris.unibe.ch/id/eprint/17996 (FactScience: 225843)

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