Thiede, Jan; Rothenbühler, Simon; Iacovache, Ioan; Langenegger, Simon M; Zuber, Benoît; Häner, Robert (2023). Supramolecular assembly of pyrene-DNA conjugates: influence of pyrene substitution pattern and implications for artificial LHCs. Organic & biomolecular chemistry, 21(39), pp. 7908-7912. Royal Society of Chemistry 10.1039/d3ob01375h
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The supramolecular self-assembly of pyrene-DNA conjugates into nanostructures is presented. DNA functionalized with different types of pyrene isomers at the 3'-end self-assemble into nano-objects. The shape of the nanostructures is influenced by the type of pyrene isomer appended to the DNA. Multilamellar vesicles are observed with the 1,6- and 1,8-isomers, whereas conjugates of the 2,7-isomer exclusively assemble into spherical nanoparticles. Self-assembled nano-spheres obtained with the 2,7-dialkynyl pyrene isomer were used for the construction of an artificial light-harvesting complex (LHC) in combination with Cy3 as the energy acceptor.
Item Type: |
Journal Article (Original Article) |
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Division/Institute: |
09 Interdisciplinary Units > Microscopy Imaging Center (MIC) 04 Faculty of Medicine > Pre-clinic Human Medicine > Institute of Anatomy 08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Thiede, Jan, Rothenbühler, Simon, Iacovache, Mircea Ioan, Langenegger, Simon Matthias, Zuber, Benoît, Häner, Robert |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry 600 Technology > 610 Medicine & health |
ISSN: |
1477-0520 |
Publisher: |
Royal Society of Chemistry |
Language: |
English |
Submitter: |
Pubmed Import |
Date Deposited: |
27 Sep 2023 10:12 |
Last Modified: |
20 Oct 2023 11:00 |
Publisher DOI: |
10.1039/d3ob01375h |
PubMed ID: |
37750811 |
BORIS DOI: |
10.48350/186630 |
URI: |
https://boris.unibe.ch/id/eprint/186630 |
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