Knörr, Pascal; Lentz, Nicolas; Albrecht, Martin (2023). Efficient additive-free formic acid dehydrogenation with a NNN-ruthenium complex. Catalysis science & technology, 13(19), pp. 5625-5631. Royal Society of Chemistry 10.1039/d3cy00512g
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A new ruthenium complex containing a pyridylidene amine-based NNN ligand was developed as a catalyst precursor for formic acid dehydrogenation, which, as a rare example, does not require basic additives to display high activity (TOF ∼10 000 h-1). Conveniently, the complex is air-stable, but sensitive to light. Mechanistic investigations using UV-vis and NMR spectroscopic monitoring correlated with gas evolution profiles indicate rapid and reversible protonation of the central nitrogen of the NNN ligand as key step of catalyst activation, followed by an associative step for formic acid dehydrogenation.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Knörr, Pascal, Lentz, Nicolas Christian Albert, Albrecht, Martin |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry |
ISSN: |
2044-4753 |
Publisher: |
Royal Society of Chemistry |
Language: |
English |
Submitter: |
Pubmed Import |
Date Deposited: |
29 Nov 2023 09:39 |
Last Modified: |
29 Nov 2023 09:49 |
Publisher DOI: |
10.1039/d3cy00512g |
PubMed ID: |
38013841 |
BORIS DOI: |
10.48350/189516 |
URI: |
https://boris.unibe.ch/id/eprint/189516 |
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