Molecular and ionic sublimation of erbium tribromide

Butman, Mikhail F; Kudin, Lev S; Motalov, Vladimir B; Kryuchkov, Artem S; Grishin, A.E.; Krämer, Karl (2009). Molecular and ionic sublimation of erbium tribromide. Russian journal of physical chemistry. A, 83(1), pp. 134-137. Moscow: MAIK Nauka/Interperiodica 10.1134/S0036024409010269

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The molecular and ionic composition of vapor over erbium tribromide sublimed from the Knudsen effusion cell and the open surface of a single crystal was studied by high-temperature mass spectrometry. The partial pressures of ErBr3 and Er2Br6 molecules in saturated vapor and the ratio between their sublimation coefficients under free vaporization conditions were determined. The enthalpies and activation energies of sublimation of ErBr3 crystals in the form of monomers and dimers were calculated. The emission of and Er2 was recorded in studies of ionic sublimation in both modes. The enthalpies of formation of gas molecules and ions were determined.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Departement of Chemistry and Biochemistry

UniBE Contributor:

Krämer, Karl

ISSN:

0036-0244

Publisher:

MAIK Nauka/Interperiodica

Submitter:

Factscience Import

Date Deposited:

04 Oct 2013 15:20

Last Modified:

05 Apr 2014 17:25

Publisher DOI:

10.1134/S0036024409010269

Web of Science ID:

000262484900026

Additional Information:

Original Russian Text © M.F. Butman, L.S. Kudin, V.B. Motalov, A.S. Kryuchkov, A.E. Grishin, K.W. Krämer, 2009, published in Zhurnal Fizicheskoi Khimii, 2009, Vol. 83, No. 1, pp. 152–155.

URI:

https://boris.unibe.ch/id/eprint/36101 (FactScience: 203255)

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