Roldan, Diego; Kaliginedi, Veerabhadrarao; Cobo, Saioa; Kolivoska, Viliam; Bucher, Christophe; Hong, Wenjing; Royal, Guy; Wandlowski, Thomas (2013). Charge Transport in Photoswitchable Dimethyldihydropyrene-Type Single-Molecule Junctions. Journal of the American Chemical Society, 135(16), pp. 5974-5977. American Chemical Society 10.1021/ja401484j
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The conductance properties of a photoswitchable
dimethyldihydropyrene (DHP) derivative have
been investigated for the first time in single-molecule
junctions using the mechanically controllable break
junction technique. We demonstrate that the reversible
structure changes induced by isomerization of a single
bispyridine-substituted DHP molecule are correlated with
a large drop of the conductance value. We found a very
high ON/OFF ratio (>104) and an excellent reversibility
of conductance switching.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Kolivoska, Viliam, Hong, Wenjing, Wandlowski, Thomas |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry |
ISSN: |
0002-7863 |
Publisher: |
American Chemical Society |
Language: |
English |
Submitter: |
Wenjing Hong |
Date Deposited: |
17 Jan 2014 09:11 |
Last Modified: |
05 Dec 2022 14:27 |
Publisher DOI: |
10.1021/ja401484j |
BORIS DOI: |
10.7892/boris.39860 |
URI: |
https://boris.unibe.ch/id/eprint/39860 |
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