Two-Dimensional Supramolecular Electron Spin Arrays

Wäckerlin, C.; Nowakowski, J.; Liu, Shi-Xia; Jaggi, Michael; Siewert, D.; Girovsky, J.; Shchyrba, A.; Hahlen, T.; Kleibert, A.; Oppeneer, P. M.; Nolting, F.; Decurtins, Silvio; Jung, T. A.; Ballav, N. (2013). Two-Dimensional Supramolecular Electron Spin Arrays. Advanced materials, 25(17), pp. 2404-2408. Wiley-VCH 10.1002/adma.201204274

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A bottom-up approach is introduced to fabricate two-dimensional self-assembled layers of molecular spin-systems containing Mn and Fe ions arranged in a chessboard lattice. We demonstrate that the Mn and Fe spin states can be reversibly operated by their selective response to coordination/decoordination of volatile ligands like ammonia (NH3).

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP)

UniBE Contributor:

Liu, Shi-Xia, Jaggi, Michael, Decurtins, Silvio

Subjects:

500 Science > 570 Life sciences; biology
500 Science > 540 Chemistry

ISSN:

0935-9648

Publisher:

Wiley-VCH

Language:

English

Submitter:

Gabriela Claudia Frei

Date Deposited:

28 Jul 2014 12:10

Last Modified:

05 Dec 2022 14:31

Publisher DOI:

10.1002/adma.201204274

PubMed ID:

23340977

Uncontrolled Keywords:

self-assembly, magnetic materials, supramolecular materials, stimuli-responsive materials, X-ray absorption spectroscopy

BORIS DOI:

10.7892/boris.46371

URI:

https://boris.unibe.ch/id/eprint/46371

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