Low-lying excited states and nonradiative processes of 9-methyl-2-aminopurine

Trachsel, Maria Angela; Lobsiger, Simon; Schär, Tobias; Leutwyler, Samuel (2014). Low-lying excited states and nonradiative processes of 9-methyl-2-aminopurine. The Journal of Chemical Physics, 140(4), 044331. American Institute of Physics 10.1063/1.4862913

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he UV spectrum of the adenine analogue 9-methyl-2-aminopurine (9M-2AP) is investigated with one- and two-color resonant two-photon ionization spectroscopy at 0.3 and 0.05 cm−1 resolution in a supersonic jet. The electronic origin at 32 252 cm−1 exhibits methyl torsional subbands that originate from the 0A′′1 (l = 0) and 1E ″ (l = ±1) torsional levels. These and further torsional bands that appear up to 000+230 cm−1 allow to fit the threefold (V 3) barriers of the torsional potentials as ∣∣V′′3∣∣=50 cm−1 in the S 0 and ∣∣V′3∣∣=126 cm−1 in the S 1 state. Using the B3LYP density functional and correlated approximate second-order coupled cluster CC2 methods, the methyl orientation is calculated to be symmetric relative to the 2AP plane in both states, with barriers of V′′3=20 cm−1 and V′3=115 cm−1. The 000 rotational band contour is 75% in-plane (a/b) polarized, characteristic for a dominantly long-axis 1ππ* excitation. The residual 25% c-axis polarization may indicate coupling of the 1ππ* to the close-lying 1 nπ* state, calculated at 4.00 and 4.01 eV with the CC2 method. However, the CC2 calculated 1 nπ oscillator strength is only 6% of that of the 1ππ* transition. The 1ππ* vibronic spectrum is very complex, showing about 40 bands within the lowest 500 cm−1. The methyl torsion and the low-frequency out-of-plane ν′1 and ν′2 vibrations are strongly coupled in the 1ππ* state. This gives rise to many torsion-vibration combination bands built on out-of-plane fundamentals, which are without precedence in the 1ππ* spectrum of 9H-2-aminopurine [S. Lobsiger, R. K. Sinha, M. Trachsel, and S. Leutwyler, J. Chem. Phys.134, 114307 (2011)]. From the Lorentzian broadening needed to fit the 000 contour of 9M-2AP, the 1ππ* lifetime is τ ⩾ 120 ps, reflecting a rapid nonradiative transition.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Departement of Chemistry and Biochemistry
13 Central Units > Services of the Rector's Office > Forum für Universität und Gesellschaft
08 Faculty of Science > Other Institutions > Teaching Staff, Faculty of Science

UniBE Contributor:

Trachsel, Maria Angela; Lobsiger, Simon; Schär, Tobias and Leutwyler, Samuel

Subjects:

500 Science
500 Science > 540 Chemistry

ISSN:

0021-9606

Publisher:

American Institute of Physics

Language:

English

Submitter:

Beatrice Niederhauser

Date Deposited:

05 Apr 2014 00:34

Last Modified:

15 Jan 2016 09:49

Publisher DOI:

10.1063/1.4862913

BORIS DOI:

10.7892/boris.47865

URI:

https://boris.unibe.ch/id/eprint/47865

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