Lanza, Arianna; Fiolka, Christoph; Fisch, Martin; Casati, N.; Skoulatos, M.; Rüegg, C.; Krämer, Karl; Macchi, Piero (2014). New magnetic frameworks of [(CuF 2 (H 2 O) 2 ) x (pyz)]. Chemical communications, 50(93), pp. 14504-14507. Royal Society of Chemistry 10.1039/C4CC06696K
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Pressure-driven orbital reordering in the quantum magnet [CuF2(H2O)2-
(pyz)], (pyz = pyrazine), dramatically affects its magnetic exchange interactions.
The crystal chemistry of this system is enriched with a new phase
above 3 GPa, surprisingly concomitant with other polymorphs. Moreover,
we discovered an unprecedented compound with a different
stoichiometry, [(CuF2(H2O)2)2(pyz)], featuring magnetic bi-layers.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Lanza, Arianna, Fiolka, Christoph, Fisch, Martin, Krämer, Karl, Macchi, Piero |
Subjects: |
500 Science > 540 Chemistry |
ISSN: |
1359-7345 |
Publisher: |
Royal Society of Chemistry |
Language: |
English |
Submitter: |
Karl Krämer |
Date Deposited: |
30 Oct 2014 16:35 |
Last Modified: |
05 Dec 2022 14:37 |
Publisher DOI: |
10.1039/C4CC06696K |
BORIS DOI: |
10.7892/boris.59676 |
URI: |
https://boris.unibe.ch/id/eprint/59676 |
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