Zhumaev, Ulmas; Pobelov, Ilya; Rudnev, Alexander; Kuzume, Akiyoshi; Wandlowski, Thomas (2014). Decoupling surface reconstruction and perchlorate adsorption on Au(111). Electrochemistry communications, 44, pp. 31-33. Elsevier 10.1016/j.elecom.2014.04.009
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On Au(111) electrodes, the investigation of ClO4− adsorption is hampered by a simultaneous surface reconstruction. We demonstrate that these two processes can be decoupled in cyclic voltammograms by a proper choice of the scan rate and of the initial potential. Our approach allowed the establishment of a relation between potentials of zero charge for the reconstructed and unreconstructed Au(111) surfaces.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) 08 Faculty of Science > Other Institutions > Teaching Staff, Faculty of Science |
UniBE Contributor: |
Zhumaev, Ulmas, Pobelov, Ilya, Rudnev, Alexander, Kuzume, Akiyoshi, Wandlowski, Thomas |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry 500 Science |
ISSN: |
1388-2481 |
Publisher: |
Elsevier |
Language: |
English |
Submitter: |
Beatrice Niederhauser |
Date Deposited: |
26 Mar 2015 10:57 |
Last Modified: |
05 Dec 2022 14:44 |
Publisher DOI: |
10.1016/j.elecom.2014.04.009 |
BORIS DOI: |
10.7892/boris.65948 |
URI: |
https://boris.unibe.ch/id/eprint/65948 |
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