Structural Studies of Transition Metal Complexes with 4,5-Bis(2-pyridylmethylsulfanyl)-4‘,5‘-ethylenedithiotetrathiafulvalene: Probing Their Potential for the Construction of Multifunctional Molecular Assemblies

Liu, Shi-Xia; Dolder, Stefan; Franz, Patrick; Neels, Antonia; Stoeckli-Evans, Helen; Decurtins, Silvio (2003). Structural Studies of Transition Metal Complexes with 4,5-Bis(2-pyridylmethylsulfanyl)-4‘,5‘-ethylenedithiotetrathiafulvalene: Probing Their Potential for the Construction of Multifunctional Molecular Assemblies. Inorganic chemistry, 42(16), pp. 4801-4803. American Chemical Society 10.1021/ic034348h

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Three divalent transition metal complexes of 4,5-bis(2-pyridylmethylsulfanyl)-4‘,5‘-ethylenedithiotetrathiafulvalene have been prepared and crystallographically characterized. The isostructural Co(II) and the Ni(II) complexes show octahedral geometries around the metal ions with the coordination sites occupied by the pyridyl nitrogen atoms and the thioether sulfur atoms of the ligand and cis coordination of the halide ions. Cyclic voltammetry reveals that the complexation leads to a small anodic shift in the first oxidation potential of the TTF system.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Departement of Chemistry and Biochemistry

UniBE Contributor:

Liu, Shi-Xia; Dolder, Stefan and Decurtins, Silvio

Subjects:

500 Science > 570 Life sciences; biology
500 Science > 540 Chemistry

ISSN:

0020-1669

Publisher:

American Chemical Society

Language:

English

Submitter:

Silvio Decurtins

Date Deposited:

20 May 2015 09:49

Last Modified:

21 May 2015 20:06

Publisher DOI:

10.1021/ic034348h

BORIS DOI:

10.7892/boris.68530

URI:

https://boris.unibe.ch/id/eprint/68530

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