Liu, Shi-Xia; Dolder, Stefan; Rusanov, Eduard B; Stoeckli-Evans, Helen; Decurtins, Silvio (2003). Novel unsymmetrically functionalized BEDT–TTF derivatives: synthesis, crystal structure and electrochemical characterization. Comptes rendus - chimie, 6(7), pp. 657-662. Elsevier 10.1016/S1631-0748(03)00118-8
![[img]](https://boris.unibe.ch/style/images/fileicons/text.png) |
Text
1-s2.0-S1631074803001188-main.pdf - Published Version Restricted to registered users only Available under License Publisher holds Copyright. Download (232kB) |
Novel functionalized bis(ethylenedithio)tetrathiafulvalene (BEDT–TTF) derivatives 4 and 5 have been synthesized in good yields from cyano precursor via a cross-coupling reaction. Their redox potentials have been studied by cyclic voltammetry in a dichloromethane solution; this indicated that they are slightly weaker electron donors than BEDT–TTF. Compound 4 has been studied by X–ray crystallography; this revealed that, in the crystal, the molecules were held together by some unconventional C–H···N and C–H···S hydrogen bonds.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Liu, Shi-Xia, Dolder, Stefan, Decurtins, Silvio |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry |
ISSN: |
1631-0748 |
Publisher: |
Elsevier |
Language: |
English |
Submitter: |
Silvio Decurtins |
Date Deposited: |
20 May 2015 10:05 |
Last Modified: |
05 Dec 2022 14:46 |
Publisher DOI: |
10.1016/S1631-0748(03)00118-8 |
BORIS DOI: |
10.7892/boris.68531 |
URI: |
https://boris.unibe.ch/id/eprint/68531 |
Actions (login required)
 |
Edit item |