Facile Synthesis of Novel Functionalized Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) Derivatives

Liu, Shi-Xia; Dolder, Stefan; Pilkington, Melanie; Decurtins, Silvio (2002). Facile Synthesis of Novel Functionalized Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) Derivatives. Journal of organic chemistry, 67(9), pp. 3160-3162. American Chemical Society 10.1021/jo0163694

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An improved and efficient synthetic route to four functionalized bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) derivatives 2−5 is reported. Tetrathiolate 1 was readily prepared from 2,2‘-bis(1,3,4,6-tetrathiapentalen-5-one) under carefully controlled conditions. Subsequent reaction of 1 with selected primary alkyl halides affords new functionalized BEDT-TTF derivatives in good yields.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Departement of Chemistry and Biochemistry

UniBE Contributor:

Liu, Shi-Xia; Dolder, Stefan and Decurtins, Silvio

Subjects:

500 Science > 570 Life sciences; biology
500 Science > 540 Chemistry

ISSN:

0022-3263

Publisher:

American Chemical Society

Language:

English

Submitter:

Silvio Decurtins

Date Deposited:

20 May 2015 10:54

Last Modified:

22 May 2015 04:44

Publisher DOI:

10.1021/jo0163694

PubMed ID:

11975588

BORIS DOI:

10.7892/boris.68541

URI:

https://boris.unibe.ch/id/eprint/68541

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