Leumann, Christian; Eschenmoser, Albert (1984). Chemistry of pyrrocorphins: methylative opening of the macrocycle between rings A and D, a side reaction in the peripheral C-methylation of a 20-methyl-pyrrocorphinate. Journal of the Chemical Society, Chemical Communications(9), p. 583. Royal Society of Chemistry 10.1039/c39840000583
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One of the minor products from the previously described peripheral -methylation of a magnesium()-20-methyl--pyrrocorphinate is a C-19-methylated 19,20-seco-corphinoid derivative which, on complexation with nickel() acetate, recyclizes to a nickel()-tetradehydro-corrinate.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Leumann, Christian |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry |
ISSN: |
0022-4936 |
Publisher: |
Royal Society of Chemistry |
Language: |
English |
Submitter: |
Christian Leumann |
Date Deposited: |
21 May 2015 09:58 |
Last Modified: |
05 Dec 2022 14:47 |
Publisher DOI: |
10.1039/c39840000583 |
Additional Information: |
Type of Work: 10.1039/C39840000583 |
BORIS DOI: |
10.7892/boris.68882 |
URI: |
https://boris.unibe.ch/id/eprint/68882 |
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