Chemistry of pyrrocorphins: synthesis of isobacteriochlorins and pyrrocorphins bearing a methyl group at the meso position between rings A and D

Hilpert, Kurt; Leumann, Christian; Davis, Anthony P.; Eschenmoser, Albert (1983). Chemistry of pyrrocorphins: synthesis of isobacteriochlorins and pyrrocorphins bearing a methyl group at the meso position between rings A and D. Journal of the Chemical Society, Chemical Communications(23), p. 1401. Royal Society of Chemistry 10.1039/c39830001401

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A sigmatropic methyl shift from the angular position C-1 in ring to the position C-20 between rings and constitutes the crucial step in syntheses leading to a 20-methyl-isobacteriochlorin and to 20-methyl-pyrrocorphins which served as substrates in the investigation presented in the accompanying communication.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Departement of Chemistry and Biochemistry

UniBE Contributor:

Leumann, Christian

Subjects:

500 Science > 570 Life sciences; biology
500 Science > 540 Chemistry

ISSN:

0022-4936

Publisher:

Royal Society of Chemistry

Language:

English

Submitter:

Christian Leumann

Date Deposited:

21 May 2015 10:15

Last Modified:

26 Jun 2016 02:04

Publisher DOI:

10.1039/c39830001401

Additional Information:

Type of Work: 10.1039/C39830001401

BORIS DOI:

10.7892/boris.68884

URI:

https://boris.unibe.ch/id/eprint/68884

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