Rapid carbon nanotubes suspension in organic solvents using organosilicon polymers

Dalcanale, Federico; Grossenbacher, Jonas; Blugan, Gurdial; Gullo, Maurizio R; Brugger, Jürgen; Tevaearai, Hendrik; Graule, Thomas; Kuebler, Jakob (2016). Rapid carbon nanotubes suspension in organic solvents using organosilicon polymers. Journal of Colloid and Interface Science, 470, pp. 123-131. Elsevier 10.1016/j.jcis.2016.02.050

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A strategy for a simple dispersion of commercial multi-walled carbon nanotubes (MWCNTs) using two organosilicones, polycarbosilane SMP10 and polysilazane Ceraset PSZ20, in organic solvents such as cyclohexane, tetrahydrofuran (THF), m-xylene and chloroform is presented. In just a few minutes the combined action of sonication and the presence of Pt(0) catalyst is sufficient to obtain a homogeneous suspension, thanks to the rapid hydrosilylation reaction between SiH groups of the polymer and the CNT sidewall. The as-produced suspensions have a particle size distribution <1μm and remain unchanged after several months. A maximum of 0.47 and 0.50mg/ml was achieved, respectively, for Ceraset in THF and SMP10 in chloroform. Possible applications as polymeric and ceramic thin films or aerogels are presented.

Item Type:

Journal Article (Original Article)

Division/Institute:

04 Faculty of Medicine > Pre-clinic Human Medicine > BioMedical Research (DBMR) > DBMR Forschung Mu35 > Forschungsgruppe Herz- und Gefässchirurgie
04 Faculty of Medicine > Pre-clinic Human Medicine > BioMedical Research (DBMR) > DBMR Forschung Mu35 > Forschungsgruppe Herz- und Gefässchirurgie

UniBE Contributor:

Tevaearai, Hendrik

Subjects:

600 Technology > 610 Medicine & health

ISSN:

0021-9797

Publisher:

Elsevier

Language:

English

Submitter:

Daniela Huber

Date Deposited:

30 Jun 2016 13:37

Last Modified:

05 Dec 2022 14:55

Publisher DOI:

10.1016/j.jcis.2016.02.050

PubMed ID:

26939076

Uncontrolled Keywords:

Aerogel; Hydrosilylation; MWCNT suspension; Polycarbosilane; Polysilazane

BORIS DOI:

10.7892/boris.81899

URI:

https://boris.unibe.ch/id/eprint/81899

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