Resonant excitation energy transfer in [Rh(bpy)3][NaCr(ox)3]ClO4

Hauser, Andreas; Riesen, Hans; Pellaux, René; Decurtins, Silvio (1996). Resonant excitation energy transfer in [Rh(bpy)3][NaCr(ox)3]ClO4. Chemical physics letters, 261(3), pp. 313-317. North-Holland 10.1016/0009-2614(96)00969-4

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Resonant fluorescence line narrowing of the R1 line of the [Cr(ox)3]3− chromophore in [Rh(bpy)3][NaCr(ox)3]ClO4 at 1.6 K neither gives rise to the usual three-line pattern nor to spectral diffusion. Instead multi-line spectra with spacings equal to the zero-field splitting of the ground state are observed. This phenomenon is attributed to efficient non-radiative resonant energy transfer within the R1 line.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Departement of Chemistry and Biochemistry

UniBE Contributor:

Decurtins, Silvio

Subjects:

500 Science > 570 Life sciences; biology
500 Science > 540 Chemistry

ISSN:

0009-2614

Publisher:

North-Holland

Language:

English

Submitter:

Silvio Decurtins

Date Deposited:

13 Jul 2016 07:56

Last Modified:

17 Jul 2016 23:56

Publisher DOI:

10.1016/0009-2614(96)00969-4

BORIS DOI:

10.7892/boris.84458

URI:

https://boris.unibe.ch/id/eprint/84458

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