Assembly of Light Harvesting Antennas through Supramolecular Polymerization of Amphiphilic Phenanthrene Oligomers

Häner, Robert; Langenegger, Simon Matthias (15 September 2016). Assembly of Light Harvesting Antennas through Supramolecular Polymerization of Amphiphilic Phenanthrene Oligomers (Unpublished). In: SCS Fall Meeting 2016.

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Efficient artificial light-harvesting antennas composed of multichromophoric array in a DNA scaffold are nowadays a key aspect in the supramolecular photochemistry [1]. Recently it was reported that the phenanthrene-pyrene supramolecular polymers can efficiently absorb photons which are transferred to the pyrene collection centre [2]. To expand this idea, 3,6-dialkynylphenanthrene trimer and new pyrene related oligomers were synthesized. As the DNA scaffolds are ideal platforms to organize chromophores the interesting point due to energy transfer is to introduce another acceptors in well-defined interchromophore distance from pyrene. This approach can be done by introducing complementary strand which contains appropriate chromophore in different position. Such a supramolecular complexes were investigated with different spectroscopic methods to prove efficient harvesting and transport of energy to the acceptor core through the intermediate donor-acceptor pyrene derivative.

Item Type:

Conference or Workshop Item (Poster)

Division/Institute:

08 Faculty of Science > Departement of Chemistry and Biochemistry

UniBE Contributor:

Häner, Robert and Langenegger, Simon Matthias

Subjects:

500 Science > 570 Life sciences; biology
500 Science > 540 Chemistry

Language:

English

Submitter:

Mariusz Kownacki

Date Deposited:

23 Sep 2016 15:23

Last Modified:

23 Sep 2016 15:27

BORIS DOI:

10.7892/boris.88411

URI:

https://boris.unibe.ch/id/eprint/88411

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