Kapat, Ajoy; Konig, Andreas; Montermini, Florian; Renaud, Philippe (2011). A Radical Procedure for the Anti-Markovnikov Hydroazidation of Alkenes. Journal of the American Chemical Society, 133(35), pp. 13890-13893. Washington, D.C.: American Chemical Society 10.1021/ja2054989
Full text not available from this repository.A one-pot procedure for the efficient hydroazidation of alkenes involving hydroboration with catecholborane followed by reaction with benzenesulfonyl azide in the presence of a radical initiator is described. The regioselectivity is controlled by the hydroboration step and corresponds in most cases to an anti-Markovnikov regioselectivity. This procedure is applicable to a wide range of alkenes and gives excellent results with 1,2-disubstituted and trisubstituted alkenes.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Renaud, Philippe |
ISSN: |
0002-7863 |
Publisher: |
American Chemical Society |
Language: |
English |
Submitter: |
Factscience Import |
Date Deposited: |
04 Oct 2013 14:26 |
Last Modified: |
05 Dec 2022 14:07 |
Publisher DOI: |
10.1021/ja2054989 |
Web of Science ID: |
000295241400033 |
URI: |
https://boris.unibe.ch/id/eprint/9389 (FactScience: 215119) |
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