Accordion-optimized DEPT experiments

Furrer, Julien; Guerra, S.; Deschenaux, R. (2011). Accordion-optimized DEPT experiments. Magnetic resonance in chemistry, 49(1), pp. 16-22. Chichester, UK: Wiley Heyden 10.1002/mrc.2701

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In this contribution, a pulse sequence is described for recording accordion-optimized DEPT experiments. The proposed ACCORDEPT experiment detects a wide range of one-bond coupling constants using accordion optimization. As a proof of concept, this strategy has been applied to a mesogen containing a large range of one-bond (1)J(CH) coupling constants associated with the various structural elements. The ACCORDEPT experiment afforded significant enhancements for the resonances with the larger 1JCH couplings, similar SNR for aliphatic resonances, but reduced SNR for aliphatic resonances as compared with the standard DEPT experiment. In addition, the ACCORDEPT is straightforward to implement, does not require any supplementary calibration procedures and can be used under automated conditions without difficulty by inexperienced users. Copyright (C) 2010 John Wiley & Sons, Ltd.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Departement of Chemistry and Biochemistry

UniBE Contributor:

Furrer, Julien

Subjects:

500 Science > 570 Life sciences; biology
500 Science > 540 Chemistry

ISSN:

0749-1581

Publisher:

Wiley Heyden

Language:

English

Submitter:

Factscience Import

Date Deposited:

04 Oct 2013 14:26

Last Modified:

13 Mar 2015 08:11

Publisher DOI:

10.1002/mrc.2701

Web of Science ID:

000285962900004

URI:

https://boris.unibe.ch/id/eprint/9526 (FactScience: 215275)

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