Ran, Ying-Fen; Blum, Carmen; Liu, Shi-Xia; Sanguinet, Lionel; Levillain, Eric; Decurtins, Silvio (2011). A tetrathiafulvalene-functionalized schiff base macrocycle: synthesis, electrochemical, and photophysical properties. Tetrahedron, 67(9), pp. 1623-1627. Kidlington, UK: Elsevier Science 10.1016/j.tet.2011.01.011
Full text not available from this repository.Highly selective formation of 2+2 macrocycle 1 from 2,5-bis(3-formyl-2-hydroxyphenyl)-1,3,4-oxadiazole and a diamine-functionalized tetrathiafulvalene derivative is reported. Its electronic properties have been studied experimentally by the combination of electrochemistry and UV-vis-NIR spectroscopy. Particularly, its largely extended pi-conjugation renders this novel macrocycle simultaneously a good multielectron donor and a strong chromophore, which is rationalized on the basis of density functional theory. (C) 2011 Elsevier Ltd. All rights reserved.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Ran, Ying-Fen, Blum, Carmen, Liu, Shi-Xia, Decurtins, Silvio |
ISSN: |
0040-4020 |
Publisher: |
Elsevier Science |
Language: |
English |
Submitter: |
Factscience Import |
Date Deposited: |
04 Oct 2013 14:26 |
Last Modified: |
05 Dec 2022 14:08 |
Publisher DOI: |
10.1016/j.tet.2011.01.011 |
Web of Science ID: |
000288044600003 |
URI: |
https://boris.unibe.ch/id/eprint/9573 (FactScience: 215330) |
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