Röthlisberger, Pascal; Kaliginediand, Veerabhadrarao; Leumann, Christian (2017). Modulation of Excess Electron Transfer through LUMO Gradients in DNA Containing Phenanthrenyl Base Surrogates. Chemistry: a European journal, 23(9), pp. 2022-2025. Wiley 10.1002/chem.201605846
![[img]](https://boris.unibe.ch/style/images/fileicons/text.png) |
Text
Roethlisberger_et_al-2017-Chemistry_-_A_European_Journal(1).pdf - Published Version Restricted to registered users only Available under License Publisher holds Copyright. Download (899kB) |
|
|
Text
Röthlisberger&Leumann_manuscript.pdf - Accepted Version Available under License Publisher holds Copyright. Download (414kB) | Preview |
|
|
Text
Supporting Information .pdf - Supplemental Material Available under License Publisher holds Copyright. Download (3MB) | Preview |
The modulation of excess electron transfer (EET) within DNA containing a dimethylaminopyrene (C-AP) as an electron donor and 5-bromouracil (BrdU) as an electron acceptor through phenanthrenyl pairs (phen-R) could be achieved by modifying the phenanthrenyl base surrogates with electron withdrawing and donating groups. Arranging the phenanthrenyl units to form a descending LUMO gradient increased the EET efficiency compared to the electron transfer through uniform LUMOs or an ascending LUMO gradient.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Röthlisberger, Pascal, Leumann, Christian |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry |
ISSN: |
1521-3765 |
Publisher: |
Wiley |
Language: |
English |
Submitter: |
Christian Leumann |
Date Deposited: |
03 Mar 2017 10:38 |
Last Modified: |
05 Dec 2022 15:03 |
Publisher DOI: |
10.1002/chem.201605846 |
Uncontrolled Keywords: |
electron transfer; oligonucleotides; phenanthrene; stacking interactions |
BORIS DOI: |
10.7892/boris.95764 |
URI: |
https://boris.unibe.ch/id/eprint/95764 |
Actions (login required)
 |
Edit item |