Exploiting Synergistic Properties of Mesoionic Carbene Complexes: Teaching Rusty Metals Challenging Catalysis

Commencement Date / Completion DateUNSPECIFIED - UNSPECIFIED
Funders [18] European Research Council
Publications Valencia Calvo, Marta; Müller-Bunz, Helge; Gossage, Robert A.; Albrecht, Martin (2016). Enhanced product selectivity promoted by remote metal coordination in acceptor-free alcohol dehydrogenation catalysis. Chemical communications, 52(16), pp. 3344-3347. Royal Society of Chemistry 10.1039/C6CC00267F
Farrell, Kevin; Melle, Philipp; Gossage, Robert A.; Müller-Bunz, Helge; Albrecht, Martin (2016). Transfer hydrogenation with abnormal dicarbene rhodium( iii ) complexes containing ancillary and modular poly-pyridine ligands. Dalton transactions, 45(11), pp. 4570-4579. Royal Society of Chemistry 10.1039/C5DT04656D
Navarro Blasco, Miquel; Li, Mo; Müller-Bunz, Helge; Bernhard, Stefan; Albrecht, Martin (2016). Donor-Flexible Nitrogen Ligands for Efficient Iridium-Catalyzed Water Oxidation Catalysis. Chemistry - a European journal, 22(20), pp. 6740-6745. Wiley-VCH 10.1002/chem.201600875
Sabater Lopez, Sara; Müller-Bunz, Helge; Albrecht, Martin (2016). Carboxylate-Functionalized Mesoionic Carbene Precursors: Decarboxylation, Ruthenium Bonding, and Catalytic Activity in Hydrogen Transfer Reactions. Organometallics, 35(13), pp. 2256-2266. American Chemical Society 10.1021/acs.organomet.6b00322
Farrell, Kevin; Müller-Bunz, Helge; Albrecht, Martin (2016). Versatile bonding and coordination modes of ditriazolylidene ligands in rhodium( iii ) and iridium( iii ) complexes. Dalton transactions, 45(40), pp. 15859-15871. Royal Society of Chemistry 10.1039/C6DT01760F
Pretorius, René; Fructos, Manuel R.; Müller-Bunz, Helge; Gossage, Robert A.; Pérez, Pedro J.; Albrecht, Martin (2016). Synthesis and catalytic applications of 1,2,3-triazolylidene gold( i ) complexes in silver-free oxazoline syntheses and C–H bond activation. Dalton transactions, 45(37), pp. 14591-14602. Royal Society of Chemistry 10.1039/C6DT02181F
Hollering, Manuela; Albrecht, Martin; Kühn, Fritz E. (2016). Bonding and Catalytic Application of Ruthenium N-Heterocyclic Carbene Complexes Featuring Triazole, Triazolylidene, and Imidazolylidene Ligands. Organometallics, 35(17), pp. 2980-2986. American Chemical Society 10.1021/acs.organomet.6b00504
Navarro Blasco, Miquel; Wang, Suxiao; Müller-Bunz, Helge; Redmond, Gareth; Farrás, Pau; Albrecht, Martin (2017). Triazolylidene Metal Complexes Tagged with a Bodipy Chromophore: Synthesis and Monitoring of Ligand Exchange Reactions. Organometallics, 36(8), pp. 1469-1478. American Chemical Society 10.1021/acs.organomet.6b00672
Vivancos Ureña, Angela; Albrecht, Martin (2017). Influence of the Linker Length and Coordination Mode of (Di)Triazolylidene Ligands on the Structure and Catalytic Transfer Hydrogenation Activity of Iridium(III) Centers. Organometallics, 36(8), pp. 1580-1590. American Chemical Society 10.1021/acs.organomet.7b00140
Valencia Calvo, Marta; Pereira, Ana; Müller-Bunz, Helge; Belderraín, Tomás R.; Pérez, Pedro J.; Albrecht, Martin (2017). Triazolylidene-Iridium Complexes with a Pendant Pyridyl Group for Cooperative Metal-Ligand Induced Catalytic Dehydrogenation of Amines. Chemistry - a European journal, 23(37), pp. 8901-8911. Wiley-VCH 10.1002/chem.201700676
Pretorius, René; Mazloomi, Zahra; Albrecht, Martin (2017). Synthesis, hemilability, and catalytic transfer hydrogenation activity of iridium(III) and ruthenium(II) complexes containing oxygen-functionalised triazolylidene ligands. Journal of organometallic chemistry, 845, pp. 196-205. Elsevier 10.1016/j.jorganchem.2017.05.014
Johnson, Chloë Jane; Albrecht, Martin (2017). Triazolylidene Iron(II) Piano-Stool Complexes: Synthesis and Catalytic Hydrosilylation of Carbonyl Compounds. Organometallics, 36(15), pp. 2902-2913. American Chemical Society 10.1021/acs.organomet.7b00349
Mazloomi, Zahra; Pretorius, René; Pàmies, Oscar; Albrecht, Martin; Diéguez, Montserrat (2017). Triazolylidene Iridium Complexes for Highly Efficient and Versatile Transfer Hydrogenation of C=O, C=N, and C=C Bonds and for Acceptorless Alcohol Oxidation. Inorganic chemistry, 56(18), pp. 11282-11298. American Chemical Society 10.1021/acs.inorgchem.7b01707
Johnson, Chloë Jane; Albrecht, Martin (2017). Piano-stool N-heterocyclic carbene iron complexes: Synthesis, reactivity and catalytic applications. Coordination Chemistry Reviews, 352, pp. 1-14. Elsevier 10.1016/j.ccr.2017.08.027
Navarro Blasco, Miquel; Smith, Christene A.; Albrecht, Martin (2017). Enhanced Catalytic Activity of Iridium(III) Complexes by Facile Modification of C,N-Bidentate Chelating Pyridylideneamide Ligands. Inorganic chemistry, 56(19), pp. 11688-11701. American Chemical Society 10.1021/acs.inorgchem.7b01654
Pretorius, René; Olguín, Juan; Albrecht, Martin (2017). Carbohydrate-Functionalized 1,2,3-Triazolylidene Complexes for Application in Base-Free Alcohol and Amine Oxidation. Inorganic chemistry, 56(20), pp. 12410-12420. American Chemical Society 10.1021/acs.inorgchem.7b01899
Petronilho, A.; Vivancos Ureña, Angela; Albrecht, Martin (2017). Ether formation through reductive coupling of ketones or aldehydes catalyzed by a mesoionic carbene iridium complex. Catalysis science & technology, 7(23), pp. 5766-5774. Royal Society of Chemistry 10.1039/c7cy01832k
Vivancos Ureña, Angela; Beller, Matthias; Albrecht, Martin (2018). NHC-Based Iridium Catalysts for Hydrogenation and Dehydrogenation of N-Heteroarenes in Water under Mild Conditions. ACS Catalysis, 8(1), pp. 17-21. American Chemical Society 10.1021/acscatal.7b03547
Vivancos Ureña, Angela; Petronilho, Ana; Cardoso, Joao; Müller-Bunz, Helge; Albrecht, Martin (2018). Unveiling the role of ancillary ligands in acceptorless benzyl alcohol dehydrogenation and etherification mediated by mesoionic carbene iridium complexes. Dalton transactions, 47(1), pp. 74-82. Royal Society of Chemistry 10.1039/C7DT04109H
Navarro Blasco, Miquel; Li, Mo; Bernhard, Stefan; Albrecht, Martin (2018). A mesoionic nitrogen-donor ligand: structure, iridium coordination, and catalytic effects. Dalton transactions, 47(3), pp. 659-662. Royal Society of Chemistry 10.1039/C7DT04555G
Navarro Blasco, Miquel; Smith, Christene A.; Li, Mo; Bernhard, Stefan; Albrecht, Martin (2018). Optimization of Synthetically Versatile Pyridylidene Amide Ligands for Efficient Iridium-Catalyzed Water Oxidation. Chemistry - a European journal, 24(24), pp. 6386-6398. Wiley-VCH 10.1002/chem.201705619
Johnson, Chloë; Albrecht, Martin (2018). Z -Selective alkyne semi-hydrogenation catalysed by piano-stool N -heterocyclic carbene iron complexes. Catalysis science & technology, 8(11), pp. 2779-2783. Royal Society of Chemistry 10.1039/C8CY00681D
Planchestainer, Matteo; Ségaud, Nathalie Sylvie Laetitia; Shanmugam, Muralidharan; McMaster, Jonathan; Paradisi, Francesca; Albrecht, Martin (2018). Carbene in Cupredoxin Protein Scaffolds: Replacement of a Histidine Ligand in the Active Site Substantially Alters Copper Redox Properties. Angewandte Chemie (International ed.), 57(33), pp. 10677-10682. Wiley-VCH 10.1002/anie.201807168
Vivancos Ureña, Angela; Segarra Almela, Maria de la Candelaria; Albrecht, Martin (2018). Mesoionic and Related Less Heteroatom-Stabilized N-Heterocyclic Carbene Complexes: Synthesis, Catalysis, and Other Applications. Chemical reviews, 118(19), pp. 9493-9586. American Chemical Society 10.1021/acs.chemrev.8b00148
Melle, Philipp; Manoharan, Yanisha; Albrecht, Martin (2018). Modular Pincer-type Pyridylidene Amide Ruthenium(II) Complexes for Efficient Transfer Hydrogenation Catalysis. Inorganic chemistry, 57(18), pp. 11761-11774. American Chemical Society 10.1021/acs.inorgchem.8b01895
Navarro Blasco, Miquel; Rosar, Vera; Montini, Tiziano; Milani, Barbara; Albrecht, Martin (2018). Olefin Dimerization and Isomerization Catalyzed by Pyridylidene Amide Palladium Complexes. Organometallics, 37(20), pp. 3619-3630. American Chemical Society 10.1021/acs.organomet.8b00422
Malan, Frederick P.; Singleton, Eric; van Rooyen, Petrus H.; Albrecht, Martin; Landman, Marilé (2019). Synthesis, Stability, and (De)hydrogenation Catalysis by Normal and Abnormal Alkene- and Picolyl-Tethered NHC Ruthenium Complexes. Organometallics, 38(13), pp. 2624-2635. American Chemical Society 10.1021/acs.organomet.9b00178
Pinto, Mara F.; Olivares Moreno, Marta; Vivancos Ureña, Angela; Guisado-Barrios, Gregorio; Albrecht, Martin; Royo, Beatriz (2019). (Di)triazolylidene manganese complexes in catalytic oxidation of alcohols to ketones and aldehydes. Catalysis science & technology, 9(10), pp. 2421-2425. Royal Society of Chemistry 10.1039/C9CY00685K
Ségaud, Nathalie; McMaster, Jonathan; van Koten, Gerard; Albrecht, Martin (2019). Imidazolylidene Cu(II) Complexes: Synthesis Using Imidazolium Carboxylate Precursors and Structure Rearrangement Pathways. Inorganic chemistry, 58(23), pp. 16047-16058. American Chemical Society 10.1021/acs.inorgchem.9b02568
Byrne, Joseph P.; Musembi, Pauline; Albrecht, Martin (2019). Carbohydrate-functionalized N-heterocyclic carbene Ru( ii ) complexes: synthesis, characterization and catalytic transfer hydrogenation activity. Dalton transactions, 48(31), pp. 11838-11847. Royal Society of Chemistry 10.1039/C9DT02614B
Corbucci, Ilaria; Zaccaria, Francesco; Heath, Rachel; Gatto, Giordano; Zuccaccia, Cristiano; Albrecht, Martin; Macchioni, Alceo (2019). Iridium Water Oxidation Catalysts Based on Pyridine‐Carbene Alkyl‐Substituted Ligands. ChemCatChem, 11(21), pp. 5353-5361. WILEY-VCH 10.1002/cctc.201901092
Olivares, Marta; Knörr, Pascal; Albrecht, Martin (2020). Aerobic dehydrogenation of amines to nitriles catalyzed by triazolylidene ruthenium complexes with O2 as terminal oxidant. Dalton transactions, 49(6), pp. 1981-1991. Royal Society of Chemistry 10.1039/C9DT04873A
Olivares, Marta; van der Ham, Cornelis J. M.; Mdluli, Velabo; Schmidtendorf, Markus; Müller-Bunz, Helge; Verhoeven, Tiny W. G. M.; Li, Mo; Niemantsverdriet, J. W. Hans; Hetterscheid, Dennis G. H.; Bernhard, Stefan; Albrecht, Martin (2020). Relevance of Chemical vs. Electrochemical Oxidation of Tunable Carbene Iridium Complexes for Catalytic Water Oxidation. European journal of inorganic chemistry, 2020(10), pp. 801-812. Wiley-VCH 10.1002/ejic.202000090
Weilhard, Andreas; Salzmann, Kevin; Navarro, Miquel; Dupont, Jairton; Albrecht, Martin; Sans, Victor (2020). Catalyst design for highly efficient carbon dioxide hydrogenation to formic acid under buffering conditions. Journal of catalysis, 385(2020), pp. 1-9. Elsevier 10.1016/j.jcat.2020.02.027
Salzmann, Kevin; Segarra, Candelaria; Albrecht, Martin (2020). Donor‐Flexible Bis(pyridylidene amide) Ligands for Highly Efficient Ruthenium‐Catalyzed Olefin Oxidation. Angewandte Chemie (International ed.), 59(23), pp. 8932-8936. Wiley-VCH 10.1002/anie.202002014
Bertini, Simone; Albrecht, Martin (2020). O -Functionalised NHC Ligands for Efficient Nickel-catalysed C–O Hydrosilylation. CHIMIA, 74(6), pp. 483-488. Schweizerische Chemische Gesellschaft 10.2533/chimia.2020.483
Mollar‐Cuni, Andres; Byrne, Joseph P.; Borja, Pilar; Vicent, Cristian; Albrecht, Martin; Mata, Jose A. (2020). Selective Conversion of Various Monosaccharaides into Sugar Acids by Additive‐Free Dehydrogenation in Water. ChemCatChem, 12(14), pp. 3746-3752. WILEY-VCH 10.1002/cctc.202000544
Navarro, Miquel; Segarra, Candela; Pfister, Tim; Albrecht, Martin (2020). Structural, Electronic, and Catalytic Modulation of Chelating Pyridylideneamide Ruthenium(II) Complexes. Organometallics, 39(13), pp. 2383-2391. American Chemical Society 10.1021/acs.organomet.0c00205
Melle, Philipp; Ségaud, Nathalie; Albrecht, Martin (2020). Ambidentate bonding and electrochemical implications of pincer-type pyridylidene amide ligands in complexes of nickel, cobalt and zinc. Dalton transactions, 49(36), pp. 12662-12673. Royal Society of Chemistry 10.1039/D0DT02482A
Melle, Philipp; Thiede, Jan; Hey, Daniela A.; Albrecht, Martin (2020). Highly Efficient Transfer Hydrogenation Catalysis with Tailored Pyridylidene Amide Pincer Ruthenium Complexes. Chemistry - a European journal, 26(58), pp. 13226-13234. Wiley-VCH 10.1002/chem.202001145
Planchestainer, Matteo; McMaster, Jonathan; Schulz, Christine; Paradisi, Francesca; Albrecht, Martin (2020). Carbene‐Induced Rescue of Catalytic Activity in Deactivated Nitrite Reductase Mutant. Chemistry - a European journal, 26(66), pp. 15206-15211. Wiley-VCH 10.1002/chem.202002444
Verhoeven, Dide G. A.; Albrecht, Martin (2020). Modular O- vs. N-coordination of pyridylidene amide ligands to iron determines activity in alcohol oxidation catalysis. Dalton transactions, 49(48), pp. 17674-17682. Royal Society of Chemistry 10.1039/d0dt02818e
Mazloomi, Zahra; Margalef, Jessica; Gil-Sepulcre, Marcos; Romero, Nuria; Albrecht, Martin; Llobet, Antoni; Sala, Xavier; Pàmies, Oscar; Diéguez, Montserrat (2020). Effect of Ligand Chelation and Sacrificial Oxidant on the Integrity of Triazole-Based Carbene Iridium Water Oxidation Catalysts. Inorganic chemistry, 59(17), pp. 12337-12347. American Chemical Society 10.1021/acs.inorgchem.0c01439
Byrne, Joseph P.; Albrecht, Martin (2020). Anion–cation synergistic metal-free catalytic oxidative homocoupling of benzylamines by triazolium iodide salts. Organic & biomolecular chemistry, 18(37), pp. 7379-7387. Royal Society of Chemistry 10.1039/D0OB01472A
Bertini, Simone; Albrecht, Martin (2020). Synthesis and Reactivity of Remarkably Stable and Nucleophilic Hydroxide-Bridged Dimetallic Nickel NHC Complexes. Organometallics, 39(18), pp. 3413-3424. American Chemical Society 10.1021/acs.organomet.0c00495
Bertini, Simone; Henryon, Dorothée; Edmunds, Andrew J. F.; Albrecht, Martin (2022). Pyridylidene Amide Ru Complex for Selective Oxidation in Organic Synthesis. Organic letters, 24(6), pp. 1378-1382. American Chemical Society 10.1021/acs.orglett.2c00177
Byrne, Joseph P; Delgado, Lidia; Paradisi, Francesca; Albrecht, Martin (2022). Carbohydrate‐Functionalized Triazolylidene Iridium Complexes: Hydrogenation Catalysis in Water with Asymmetric Induction. ChemCatChem, 14(7), e202200086. WILEY-VCH 10.1002/cctc.202200086

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