Exploring Intramolecular Methyl–Methyl Coupling on a Metal Surface for Edge-Extended Graphene Nanoribbons

Qiu, Zijie; Sun, Qiang; Wang, Shiyong; Barin, Gabriela Borin; Dumslaff, Bastian; Ruffieux, Pascal; Müllen, Klaus; Narita, Akimitsu; Fasel, Roman (2021). Exploring Intramolecular Methyl–Methyl Coupling on a Metal Surface for Edge-Extended Graphene Nanoribbons. Organic materials, 03(02), pp. 128-133. Thieme 10.1055/s-0041-1726295

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Intramolecular methyl-methyl coupling on Au (111) is explored as a new on-surface protocol for edge extension in graphene nanoribbons (GNRs). Characterized by high-resolution scanning tunneling microscopy, noncontact atomic force microscopy, and Raman spectroscopy, the methyl–methyl coupling is proven to indeed proceed at the armchair edges of the GNRs, forming six-membered rings with sp3- or sp2-hybridized carbons.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP)

UniBE Contributor:

Fasel, Roman

Subjects:

500 Science > 530 Physics
500 Science > 540 Chemistry

ISSN:

2625-1825

Publisher:

Thieme

Language:

English

Submitter:

Roman Fasel

Date Deposited:

17 Feb 2022 15:51

Last Modified:

29 Jan 2024 09:42

Publisher DOI:

10.1055/s-0041-1726295

BORIS DOI:

10.48350/164882

URI:

https://boris.unibe.ch/id/eprint/164882

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