Radical chain reactions involving 9-alkyl-9-borafluorenes

Gorokhovik, Ioulia; Rieder, Samuel; Povie, Guillaume; Renaud, Philippe (2014). Radical chain reactions involving 9-alkyl-9-borafluorenes. Arkivoc, 2014(3), pp. 274-286. Michigan Publishing 10.3998/ark.5550190.p008.548

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The preparation of 9-alkyl-9-borafluorenes and their use as radical precursors in chain reactions were investigated. These organoboranes were found to be excellent precursors of primary and secondary alkyl radicals. Reactions were readily initiated by traces of oxygen and efficient processes involving sulfonyl-based radical traps were discovered. Due to the very high reactivity of the intermediate 9-H and 9-alkyl-9-borafluorenes, problems of reproducibility were identified.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Departement of Chemistry and Biochemistry

UniBE Contributor:

Gorokhovik, Ioulia; Rieder, Samuel; Povie, Guillaume and Renaud, Philippe

Subjects:

500 Science > 570 Life sciences; biology
500 Science > 540 Chemistry

ISSN:

1551-7012

Publisher:

Michigan Publishing

Language:

English

Submitter:

Philippe Renaud

Date Deposited:

01 Sep 2014 12:03

Last Modified:

07 Jan 2016 08:15

Publisher DOI:

10.3998/ark.5550190.p008.548

BORIS DOI:

10.7892/boris.55022

URI:

https://boris.unibe.ch/id/eprint/55022

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