Gorokhovik, Ioulia; Rieder, Samuel; Povie, Guillaume; Renaud, Philippe (2014). Radical chain reactions involving 9-alkyl-9-borafluorenes. Arkivoc, 2014(3), pp. 274-286. Michigan Publishing 10.3998/ark.5550190.p008.548
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The preparation of 9-alkyl-9-borafluorenes and their use as radical precursors in chain reactions were investigated. These organoboranes were found to be excellent precursors of primary and secondary alkyl radicals. Reactions were readily initiated by traces of oxygen and efficient processes involving sulfonyl-based radical traps were discovered. Due to the very high reactivity of the intermediate 9-H and 9-alkyl-9-borafluorenes, problems of reproducibility were identified.
Item Type: |
Journal Article (Original Article) |
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Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Gorokhovik, Ioulia, Rieder, Samuel, Povie, Guillaume, Renaud, Philippe |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry |
ISSN: |
1551-7012 |
Publisher: |
Michigan Publishing |
Language: |
English |
Submitter: |
Philippe Renaud |
Date Deposited: |
01 Sep 2014 12:03 |
Last Modified: |
05 Dec 2022 14:36 |
Publisher DOI: |
10.3998/ark.5550190.p008.548 |
BORIS DOI: |
10.7892/boris.55022 |
URI: |
https://boris.unibe.ch/id/eprint/55022 |
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