Electrochemical control of a non-covalent binding between ferrocene and beta-cyclodextrin

Kolivoska, Viliam; Mohos, Miklos; Pobelov, Ilya; Rohrbach, Simon; Yoshida, Koji; Hong, Wenjing; Fu, Yongchun; Moreno, Pavel; Mészáros, Gábor; Broekmann, Peter; Hromadová, M.; Sokolová, R.; Valášek, M.; Wandlowski, Thomas (2014). Electrochemical control of a non-covalent binding between ferrocene and beta-cyclodextrin. Chemical communications, 50(79), pp. 11757-11759. Royal Society of Chemistry 10.1039/C4CC04102J

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The forces required for the detachment of ferrocene (Fc) from β-cyclodextrin (βCD) in a single host (βCD)–guest (Fc) complex were investigated using force spectroscopy under electrochemical conditions. The redox state of the guest Fc moiety as well as the structure of the supporting matrix was found to decisively affect the nanomechanical properties of the complex.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Departement of Chemistry and Biochemistry
10 Strategic Research Centers > Center for Space and Habitability (CSH)

UniBE Contributor:

Kolivoska, Viliam; Mohos, Miklos; Pobelov, Ilya; Yoshida, Koji; Hong, Wenjing; Fu, Yongchun; Moreno, Pavel; Mészáros, Gábor; Broekmann, Peter and Wandlowski, Thomas

Subjects:

500 Science > 570 Life sciences; biology
500 Science > 540 Chemistry
500 Science
500 Science > 520 Astronomy

ISSN:

1359-7345

Publisher:

Royal Society of Chemistry

Language:

English

Submitter:

Beatrice Niederhauser

Date Deposited:

26 Mar 2015 10:45

Last Modified:

27 Mar 2015 02:22

Publisher DOI:

10.1039/C4CC04102J

BORIS DOI:

10.7892/boris.65945

URI:

https://boris.unibe.ch/id/eprint/65945

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