Valencia Calvo, Marta; Müller-Bunz, Helge; Gossage, Robert A.; Albrecht, Martin (2016). Enhanced product selectivity promoted by remote metal coordination in acceptor-free alcohol dehydrogenation catalysis. Chemical communications, 52(16), pp. 3344-3347. Royal Society of Chemistry 10.1039/C6CC00267F
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A bimetallic [Ir3+]2 complex was synthesized based on a bridging 1,2,3-triazole ligand that coordinates to one Cp*Ir unit as N,N-bidentate chelate, and to the other as a C,C-bidentate ligand. When compared to monometallic homologues, the bimetallic complex shows greatly enhanced product selectivity for the acceptorless dehydrogenation of alcohols; spectroscopic and electrochemical analysis suggest significant alteration of the metal properties in the bimetallic system compared to the monometallic species, which offers a rationale for the observed high selectivity.
Item Type: |
Journal Article (Original Article) |
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Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Valencia Calvo, Marta, Albrecht, Martin |
Subjects: |
500 Science > 540 Chemistry |
ISSN: |
1359-7345 |
Publisher: |
Royal Society of Chemistry |
Funders: |
[18] European Research Council |
Projects: |
[1134] Exploiting Synergistic Properties of Mesoionic Carbene Complexes: Teaching Rusty Metals Challenging Catalysis |
Language: |
English |
Submitter: |
Eik Szee Goh Aschauer |
Date Deposited: |
19 Jan 2017 16:01 |
Last Modified: |
05 Dec 2022 15:01 |
Publisher DOI: |
10.1039/C6CC00267F |
BORIS DOI: |
10.7892/boris.93722 |
URI: |
https://boris.unibe.ch/id/eprint/93722 |
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