Synthesis of Responsive Two-Dimensional Polymers via Self-Assembled DNA Networks

Yu, Hao; Alexander, Duncan T. L.; Aschauer, Ulrich Johannes; Häner, Robert (2017). Synthesis of Responsive Two-Dimensional Polymers via Self-Assembled DNA Networks. Angewandte Chemie (International ed.), 56(18), pp. 5040-5044. Wiley-VCH 10.1002/ange.201701342

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Despite a growing interest in two-dimensional polymers, their rational synthesis remains a challenge. The solution-phase synthesis of a two-dimensional polymer is reported. A DNA-based monomer self-assembles into a supramolecular network, which is further converted into the covalently linked two-dimensional polymer by anthracene dimerization. The polymers appear as uniform monolayers, as shown by AFM and TEM imaging. Furthermore, they exhibit a pronounced solvent responsivity. The results demonstrate the value of DNA-controlled self-assembly for the formation of two-dimensional polymers in solution.

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