Mikhail, Patric; Basler, Reto; Hulliger, Jürg (1999). Czochralski growth and spectroscopic investigations of Yb3+, La3+:Na2SO4(I) and Nd3+:Na2SO4(I). Journal of materials research, 14(10), pp. 4093-4097. Cambridge University Press 10.1557/JMR.1999.0552
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Ln3+-stabilized Na2SO4 (phase I) single crystals were grown by the Czochralski method. Differential thermal analysis revealed the influence of the ionic radius of Ln3+ on the stabilization of Na2SO4(I). Distribution coefficients (∼0.8–1.1) were measured by the inductively coupled plasma optical emission spectroscopy method and x-ray fluorescence spectroscopy. Spectroscopic investigations yielded absorption cross sections of 0.6 × 10−20 cm2 (π-polarized, 928.5 nm) and 1.5 × 10−20 cm2 (π-polarized, 797.3 nm) for Yb3+, La3+:Na2SO4 and Nd3+:Na2SO4, respectively. Crystal growth of Gd3+-stabilized Na2SO4(I) provides an interesting new material for stimulated Raman scattering experiments.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Hulliger, Jürg |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry |
ISSN: |
0884-2914 |
Publisher: |
Cambridge University Press |
Language: |
English |
Submitter: |
Marceline Brodmann |
Date Deposited: |
21 Jul 2020 13:24 |
Last Modified: |
05 Dec 2022 15:13 |
Publisher DOI: |
10.1557/JMR.1999.0552 |
BORIS DOI: |
10.7892/boris.115317 |
URI: |
https://boris.unibe.ch/id/eprint/115317 |
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