Rothenbühler, Simon; Bösch, Caroline; Langenegger, Simon Matthias; Liu, Shi-Xia; Häner, Robert (5 October 2018). Water-Soluble Supramolecular Polymers Based on a Redox-Active Bolaamphiphile (Unpublished). In: Swiss Chemical Society Polycoll 2018. EPFL Lausanne. 05.10.2018.
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A low optical bandgap and fullerene-like electron affinity of functionalized cyclopenta[hi]aceanthrylene (cypac) was reported and potential applications as electron acceptors in organic solar cells are suggested among others.[1] In this work, a water-soluble, bolaamphiphilic cypac derivative with a low-lying LUMO and intense absorption bands over an extended range of the UV-visible spectral region has been synthesized.[2] Self-assembly of cypac-bis-phosphate in aqueous medium leads to the formation of a supramolecular polymer with a vesicular morphology. The electronic properties of the monomer remain largely intact upon supramolecular polymer formation, as evidenced by UV-vis and cyclic voltammetry measurements.
Item Type: |
Conference or Workshop Item (Poster) |
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Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Rothenbühler, Simon, Bösch, Caroline, Langenegger, Simon Matthias, Liu, Shi-Xia, Häner, Robert |
Subjects: |
500 Science > 540 Chemistry |
Language: |
English |
Submitter: |
Simon Rothenbühler |
Date Deposited: |
10 Oct 2018 10:30 |
Last Modified: |
05 Dec 2022 15:18 |
BORIS DOI: |
10.7892/boris.120406 |
URI: |
https://boris.unibe.ch/id/eprint/120406 |
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