Furrer, Julien (2020). Old and new experiments for obtaining quaternary-carbon-only NMR spectra. Applied spectroscopy reviews, 56(2), pp. 128-142. Taylor & Francis 10.1080/05704928.2020.1756838
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In this review, several Nuclear Magnetic Resonance (NMR) pulse sequences aimed at obtaining quaternary-carbon-only (Cq only) 13C spectra were evaluated both theoretically and experimentally. A new experiment, the Improved Quaternary Carbon Detection (iQCD) that improves the performances of the state-of-the-art Subsequent Editing using a Multiple Quantum Trap-90 (SEMUT-90) pulse sequence is also proposed and described. Compared to the latter, the iQCD sequence permits using shorter tip angles for the first carbon pulse to allow for a faster repetition rate and better sensitivity. With concentrated sample and by taking advantage of the high sensitivity of cryogenically cooled probeheads, artifacts-free quaternary-carbon-only spectra can be obtained with very few scans. These attributes make the iQCD NMR experiment attractive for 13C analysis of mixtures of medium-sized molecules and quaternary carbon-rich synthetic products.
Item Type: |
Journal Article (Review Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Furrer, Julien |
Subjects: |
500 Science > 540 Chemistry |
ISSN: |
0570-4928 |
Publisher: |
Taylor & Francis |
Language: |
English |
Submitter: |
Julien Henri Lucien Furrer |
Date Deposited: |
17 Jul 2020 15:40 |
Last Modified: |
05 Dec 2022 15:39 |
Publisher DOI: |
10.1080/05704928.2020.1756838 |
BORIS DOI: |
10.7892/boris.145251 |
URI: |
https://boris.unibe.ch/id/eprint/145251 |
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