Racioppi, Stefano; Andrzejewski, Michal; Colombo, Valentina; Sironi, Angelo; Macchi, Piero (2020). Different Metallophilic Attitudes Revealed by Compression. Inorganic chemistry, 59(4), pp. 2223-2227. American Chemical Society 10.1021/acs.inorgchem.9b02852
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Two isostructural coordination polymers with coinage metal(I) cationswere compressed with the purpose of testing interactions between chains, which maytrigger metallophilic interactions or otherwise expand the metal coordination. DFTcalculations and X-ray diffraction studies reveal an extraordinary difference betweenAg(I) and Cu(I) in homologous compounds. Argentophilic interactions are favored bya mild compression, and atP= 7.94 GPa, the Ag−Ag distance matches the value ofmetallic silver. On the other hand, no cuprophilic interaction is activated even bycompression up to 8 GPa, and Cu−Cu distances remain outside the van der Waalsspheres.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Racioppi, Stefano, Andrzejewski, Michal |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry 500 Science |
ISSN: |
0020-1669 |
Publisher: |
American Chemical Society |
Language: |
English |
Submitter: |
Simon Grabowsky |
Date Deposited: |
17 Feb 2021 15:12 |
Last Modified: |
05 Dec 2022 15:47 |
Publisher DOI: |
10.1021/acs.inorgchem.9b02852 |
PubMed ID: |
31999110 |
BORIS DOI: |
10.48350/152261 |
URI: |
https://boris.unibe.ch/id/eprint/152261 |
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